Please help this huge packet is due tomorrow

What is the first quartile of the data set? 10, 11, 12, 15, 17, 19, 22, 24, 29, 33, 38 a. 12 b. 19 c. 29 d. 10

Consider the reaction 2x2y2+z2⇌2x2y2z which has a rate law of rate= k[x2y2][z2] select a possible mechanism for the reaction.

A3cm×3cm\greend{3\,\text{cm} \times 3\,\text{cm}} 3cm×3cm start color greend, 3, space, c, m, times, 3, space, c, m, end color greend rectangle sits inside a circle with radius of 4cm\blued{4\,\text{cm}} 4cm start color blued, 4, space, c, m, end color blued . what is the area of the shaded region? round your final answer to the nearest hundredth.