1. A volume of 120.0 liters of a gas is prepared at a pressure of 400.0 mm Hg and a temperature 100.0 °C. The gas is placed into a tank under high pressure. When the tank cools to 10.0°C,
the pressure of the gas is 20.0 mm Hg. What is the volume of the gas?

There are two steps in the usual industrial preparation of acrylic acid, the immediate precursor of several useful plastics. in the first step, calcium carbide and water react to form acetylene and calcium hydroxide: cac2 (s) + 2h2o (g) → c2h2 (g) + caoh2 (s) =δh−414.kj in the second step, acetylene, carbon dioxide and water react to form acrylic acid: 6c2h2 (g) + 3co2 (g) + 4h2o (g) → 5ch2chco2h (g) =δh132.kj calculate the net change in enthalpy for the formation of one mole of acrylic acid from calcium carbide, water and carbon dioxide from these reactions. round your answer to the nearest kj .