EASY
why does measured current differ from calculated current

No component is perfect. All have tolerances that can vary. If you construct a simple circuit where a 10 volt power supply feeds a 10 ohm resistor, you would expect to measure a current of one ampere. BUT - the wiring has some resistance too. This adds perhaps 0.1 ohms to the circuit. The resistor has a +-5% tolerance. If it is 5% high, it may measure 10.5 ohms. That's a total circuit resistance of 10.6 ohms. The power supply may have a tolerance of +-1%. Suppose it's 1% low. That's an output of 9.9 volts in real life. So you have 9.9 volts dropped across 10.6 ohms. you will measure closer to 0.934 amps instead of 1.000 amps. To make matters worse, most electronic components have a temperature coefficient, that is, their values change with different temperatures. You may get a completely different reading tomorrow if the temperature is different! Finally, with current measurements in particular, you are inserting the ammeter in series with the circuit under test. Ammeters have some inherent resistance too, so by putting the ammeter in the circuit, you are changing the very current you are trying to measure (a little)! Oh yeah, the ammeter has a tolerance too. Its reading may be off a little even if everything else is perfect. Sometimes you have to wonder how we get a decent reading at all. Fortunately the errors are usually fairly small, and not all tolerances are off in the same direction or off the maximum amount. They tend to cancel each other out somewhat. BUT - in rare circumstances everything CAN happen like I said, and the error can be huge.

Explanation:

as given the equation is

2al + 6 hcl > 2 alcl3 + 3 h2(g)

as per equation two moles of aluminum reacts with six moles of hcl to give two moles of alcl3 and three moles of hydrogen gas

given: three moles of al are present and 7 moles of hcl

for three moles of aluminum nine moles of hcl will be required

however as 7 moles of hcl are present so the limiting reagent is hcl

hcl is going to decide the number of moles of product formed

when six moles of hcl are present = 3 moles of h2 are formed

when one mole of hcl is present == 3/6 mole sof h2 will be formed

when 7 moles of hcl are present = 3 x 7/ 6 moles of h2 will be formed = 3.5 moles of h2

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 :

equation 2 :

equation 3 :

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 :

let us add equation 1 & 4

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol