Three mixtures were prepared from three very narrow molar mass distribution polystyrene samples with molar masses of 10,000, 30,000 and 100,000 g mol−1 as indicated below: (a) Equal numbers of molecules of each sample (b) Equal masses of each sample (c) By mixing in the mass ratio 0.145:0.855 the two samples with molar masses of 10,000 and 100,000 g mol−1 For each of the mixtures, calculate the number-average and weight-average molar masses and comment upon the meaning of the values.

(a). 46,666.7 g/mol; 78,571.4 g/mol

(b). 86950g/mol; 46,666.7 g/mol.

(c). 86950g/mol; 43,333.33 g/mol

Explanation:

So, we are given the molar masses for the three samples as: 10,000, 30,000 and 100,000 g mol−1.

Thus, the equal number of molecule in each sample = ( 10,000 + 30,000 + 100,000 ) / 3 = 46,666.7 g/mol.

The average molar mass = [ ( 10,000)^2 + (30,000)^2 + 100,000)^2] ÷ 10,000 + 30,000 + 100,000 = 78,571. 4 g/mol.

(b). The equal masses of each sample = 3/[ ( 1/ 10,000) + (1/30,000 ) + (1/100,000) ] = 20930.23 g/mol.

Average molar mass = ( 10,000 + 30,000 + 100,000 ) / 3 = 46,666.7 g/mol.

(c). Equal masses of the two samples = (0.145 × 10,000) + (0.855 × 100,000)/ 0.145 + 0.855 = 86950g/mol.

The weight average molar mass = 1.7 + 10,000 + 100,000/ 1.7 + 1 = 43,333.33 g/mol.

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