A gas sample in a rigid container at 455 k is cooled to 273 k where it has a pressure of 1 atm. What was the original pressure of the gas in mmHg

What is the typical rotational frequency frot for a molecule like n2 at room temperature (25∘c)? assume that d for this molecule is 1å=10−10m. take the total mass of an n2 molecule to be mn2=4.65×10−26kg. you will need to account for rotations around two axes (not just one) to find the correct frequency. express frot numerically in hertz, to three significant figures.