How does vibrational energy contribute to a reaction?

Which statement is best described as a atom

Kc = 0.040 for the system below at 450oc. if a reaction is initiated with 0.40 mole of cl2 and 0.40 mole of pcl3 in a 2.0 liter container, what is the equilibrium concentration of cl2 in the same system? pcl5(g) ⇄ pcl3(g) + cl2(g)

Compare the equilibrium constants for the systems shown in the table. which favors products the most? which favors products the least? rank these systems in order from most to least in terms of favoring products rather than reactants. d > b > a > c c > a > b > d b > c > d > a a > d > c > b