The structure in the brain responsible for memory and new learning is the

Hippocampus

Explanation:

The Hippocampus played a really crucial role in consolidating information from our recent memory to our long-term memory (The more often we got exposed to that information,  the more likely it will be transferred to the long-term memory)

On top of that, Hippocampus also determine how well a person could use his/her  spatial memory and how fast they could understand a conceptual information.

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