What does the second law of thermodynamics state?

The second law of thermodynamics implies that thermodynamic processes in macroscopic systems can be predicted more accurately than in microscopic systems, because they are essentially statistical processes on more or less independently moving particles. The law of large numbers from the probability theory states that the relative deviations from statistical averages become smaller as the number of particles becomes larger. This law also means that self-organization in a chaotic system is only possible if energy is added.

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