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The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Clothing made of several thin layers of fabric with trapped air in between, often called ski clothing, is commonly used in cold climates because it is light, fashionable, and a very effective thermal insulator. so it is no surprise that such clothing has largely replaced thickand heavy old-fashioned coats. (a) consider a jacket made of five layers of 0.1-mm-thick synthetic fabric (k = 0.13 w/m·°c) with 1.5-mm-thick air space (k = 0.026 w/m·°c) between the layers. assuming the inner surface temperature of the jacket to be 28°c and the surface area to be 1.25 m2, determine the rate of heat loss through the jacket when the temperature of the outdoors is 0°c and the heat transfer coefficient at the outer surface is 25 w/m2·°c. (b) what would your response be if the jacket is made of a single layer of 0.5-mm-thick synthetic fabric? what should be the thickness of a wool fabric (k = 0.035 w/m·°c) if the person is to achieve the same level of thermal comfort wearing a thick wool coat instead of a five-layer ski jacket?

Why does lightning travel from clouds to the ground?