Not a homework question, but what is the difference between the equations below? I have seen both of them while studying and don't know which one to use.

Occurs when an energy source transfers heat directly to another subject space; an example would be an object becoming warm by sitting in the sunshine

Some material consisting of a collection of microscopic objects is kept at a high temperature. a photon detector capable of detecting photon energies from infrared through ultraviolet observes photons emitted with energies of 0.3 ev, 0.5 ev, 0.8 ev, 2.0ev, 2.5ev, and 2.8ev. these are the only photon energies observed. (a) draw and label a possible energy-level diagram for one of the microscopic objects, which has four bound states. on the diagram, indicate the transitions corresponding to the emitted photons. explain briefly. (b) would a spring–mass model be a good model for these microscopic objects? why or why not? (c) the material is now cooled down to a very low temperature, and the photon detector stops detecting photon emissions. next, a beam of light with a continuous range of energies from infrared through ultraviolet shines on the material, and the photon detector observes the beam of light after it passes through the material. what photon energies in this beam of light are observed to be significantly reduced in intensity (“dark absorption lines”)? explain briefly.

Acommercial refrigerator with refrigerant-134a as the working fluid is used to keep the refrigerated space at -35°c by rejecting waste heat to cooling water that enters the condenser at 18°c at a rate of 0.25 kg/s and leaves at 26°c. the refrigerant enters the condenser at 1.2 mpa and 50°c. if the compressor consumes 3.3 kw of power, determine (a) the mass flow rate of the refrigerant, (b) the refrigeration load, (c) the cop, and (d) the minimum power input to the compressor for the same refrigeration load.