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How are calculation for velocity and speed different

Modern physics a photon emitted from an excited hydrogen atom has an energy of 3.02 electron volts. which electron energy-level transition would produce this photon? a. n=1 to n=6 b. n=2 to n=6 c. n=6 to n=1 d. n=6 to n=2 i chose b but the correct answer is d can someone tell me why? and what's the difference?

Which of these has some mechanical energy? a. an atom b. heat inside earth c. a book on a shelf d. the fire from a lit match