What would happen to a vacant lot in your community if it were left alone for the next 25 years.

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.

Dinate system, and a charge q = - 2.00 nc is placed s2 10 n> c. (a) what is the change in electric potential energy when the dipole moment of a molecule changes its orientation with respect to es from parallel to perpendicular? (b) at what absolute temperature t is the average translational kinetic energy 32 kt of a molecule equal to the change in potential energy calculated in part(: abovethistemperature,thermalagitationprevents the dipoles from aligning with the electric field.) placed in a uniform electric field e with magnitude 1.6 * 6 on the positive x-axis at x = 4.00 cm. (a) if a third charge q3 = +6.00 nc is now placed at the point x = 4.00 cm, y = 3.00 cm, find the x- and y-components of the total force exerted on this charge by the other two. (b) find the magnitude and direction of figure p21.62 ll uu 21.55 . torque on a dipole. an electric dipole with dipole moment ps is in a uniform external electric field es. (a) find the orientations of the dipole for which the torque on the dipole is zero. (b) which of the orientations in part (a) is stable, and which is unstable? (hint: consider a small rotation away from the equi- librium position and see what happens.) (c) show that for the stable orientation in part (b), the dipole’s own electric field tends to oppose the external field. 21.62 ..

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