Plz help me
15 pt for 1st 10 for 2nd

What happens to atoms and chemical bonds during a reaction?

As part of an industrial process, air as an ideal gas at 10 bar, 400k expands at steady state through a valve to a pressure of 4 bar. the mass flow rate of air is 0.5 kg/s. the air then passes through a heat exchanger where it is cooled to a temperature of 295k with negligible change in pressure. the valve can be modeled as a throttling process, and kinetic and potential energy effects can be neglected. (a) for a control volume enclosing the valve and heat exchanger and enough of the local surroundings that the heat transfer occurs at the ambient temperature of 295 k, determine the rate of entropy production, in kw/k. (b) if the expansion valve were replaced by an adiabatic turbine operating isentropically, what would be the entropy production? compare the results of parts (a) and (b) and discuss.

Aheat engine running backward is called a refrigerator if its purpose is to extract heat from a cold reservoir. the same engine running backward is called a heat pump if its purpose is to exhaust warm air into the hot reservoir. heat pumps are widely used for home heating. you can think of a heat pump as a refrigerator that is cooling the already cold outdoors and, with its exhaust heat qh, warming the indoors. perhaps this seems a little silly, but consider the following. electricity can be directly used to heat a home by passing an electric current through a heating coil. this is a direct, 100% conversion of work to heat. that is, 19.0 \rm kw of electric power (generated by doing work at the rate 19.0 kj/s at the power plant) produces heat energy inside the home at a rate of 19.0 kj/s. suppose that the neighbor's home has a heat pump with a coefficient of performance of 4.00, a realistic value. note: with a refrigerator, "what you get" is heat removed. but with a heat pump, "what you get" is heat delivered. so the coefficient of performance of a heat pump is k=qh/win. an average price for electricity is about 40 mj per dollar. a furnace or heat pump will run typically 200 hours per month during the winter. what does one month's heating cost in the home with a 16.0 kw electric heater? what does one month's heating cost in the home of a neighbor who uses a heat pump to provide the same amount of heating?