How is a reaction described when a chemical reaction uses up energy

The consumption of fossil fuels could be

Suppose a wheel with a tire mounted on it is rotating at the constant rate of 2.15 times a second. a tack is stuck in the tire at a distance of 0.373 m from the rotation axis. noting that for every rotation the tack travels one circumference (a) find the tack's tangential speed. (b) what is the tacks radial acceleration?

During which interval are the persons represented by the graph not moving? a) 0 to 0.5 hrs b) 1.5 to 2 hrs c) 2 to 2.5 hrs d) 4.5 to 5 hrs