The two alternative chair conformations of cis-2-bromocyclohexanamine differ in their gibbs free energy. using the data for δg (axial-equatorial) for monosubstituted cyclohexanes at room temperature (25ºc): axial → equatorial group δg° (kj/mol) group δg° (kj/mol) -0.8 -5.9 -2.4 -7.3 -3.9 1,2-gauche 3.8 calculate the absolute value of the difference in the gibbs free energy between the alternative chair conformations. kj/mol which group in this compound is in axial position in the energetically preferred chair conformation?

In a steady-flow steam power plant system, two adiabatic high-pressure and low-pressure turbines ane used to generate power. superheated steam enters the high-pressure turbine at 8 mpa and 550°c. the steam expands in the high-pressure turbine to a saturated vapor at 3 mpa. in order to increase the powe generation of the power plant, another steam turbine working in a lower pressure ranges is deployed. the outlet vapor from the first turbine is heated up at a boiler to the temperature of 500 c at the constant pressure of first turbine's outlet (3 mpa). then, the vapor enters the second turbine and produces extra work. the exit conditions of the second turbine are 5o kpa and 90 percent quality. if the total power output of the power plant is 25 mw, determine a) the mass flow rate of the water (kg/s). b) heat transfer rate in the boiler (mw). (30 points) 3 mpa 00 c 8 mpa s0 c high pres turbine low pres boiler turbine 50 kpa 3 mpa 09 saturated vapor t heat engine, shown in the figure, operates between high temperature and low temperature of through a heat 4. a carnot tn and tu respectively. this heat engine receives energy from a heat reservoir at t exchanger where the heat transferred is proportional to the temperature difference as ? = k (z,-7, ). it rejects heat at a given low temperature tl. to design the heat engine for maximum work output, find the high temperature, th, as a function of tes and t. (15 points) qe

How are calculation for velocity and speed different

Ablock of mass m = 2.5 kg is attached to a spring with spring constant k = 790 n/m. it is initially at rest on an inclined plane that is at an angle of 28 degrees with respect to the horizontal, and the coefficient of kinetic friction between the block and the plane is k = 0.14. in the initial position, where the spring is compressed by a distance of a = 0.18 m, the mass is at its lowest position and the spring is compressed the maximum amount. take the initial gravitational energy of the block as zero. b) if the spring pushes the block up the incline, what distance, l, in meters will the block travel before coming to rest? the spring remains attached to both the block and the fixed wall throughout its motion.