The law of reflection is quite useful for mirrors and other flat, shiny surfaces. (This sort of reflection is called specular reflection). However, you've likely been told that when you look at something, you are seeing light reflected from the object that you are looking at. This is reflection of a different sort of diffuse reflection. Suppose that the spotlight shines so that different parts of the beam reflect off of different two surfaces, one inclined at an angle alpha (from the horizontal) and one inclined at an angle beta. What would the angular separation between the rays reflected from the two surfaces?

The particle in a two-dimensional well is a useful model for the motion of electrons around the indole ring (3), the conjugated cycle found in the side chain of tryptophan. we may regard indole as a rectangle with sides of length 280 pm and 450 pm, with 10 electrons in the conjugated p system. as in case study 9.1, we assume that in the ground state of the molecule each quantized level is occupied by two electrons. (a) calculate the energy of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels. 9.27 electrons around the porphine ring (4), the conjugated macrocycle that forms the structural basis of the heme group and the chlorophylls. we may treat the group as a circular ring of radius 440 pm, with 20 electrons in the conjugated system moving along the perimeter of the ring. as in exercise 9.26, assume that in the ground state of the molecule quantized each level is occupied by two electrons. (a) calculate the energy and angular momentum of an electron in the highest occupied level. (b) calculate the frequency of radiation that can induce a transition between the highest occupied and lowest unoccupied levels.