Someone please help idk if I did this right the questions a-d

If 21.2 kcals of energy is released by this reaction, how many kj does the reaction release? (1 cal 4.184 j)

Aball tossed vertically upward from the ground next to a building passes the bottom of a window 1.8 s after being tossed and passes the top of the window 0.20 s later. the window is 2.0 m high from top to bottom. what was the ball's initial velocity? the unit vector j^ is directed upward. how far is the bottom of the window from the launch position? how high does the ball rise above the launch position?

Abanked road comer of radius 146 m is to be constructed. if the comer is designed for vehicles moving with a speed of 20.0 m/s, what should the banking angle be, in units of degrees?