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Physics, 22.02.2020 03:06 fattypickeltoefungus

Assuming that in free-radical polymerization the rate coefficients for initiator dissociation, propagation and termination can be replaced by the appropriate Arrhenius expressions kd = Ad exp (āˆ’Ed /RT) kp = Ap exp (āˆ’Ep /RT) kt = At exp (āˆ’Et /RT) calculate the changes in the rate of polymerization and the degree of polymerization caused by increasing the temperature of polymerization of styrene in benzene, initiated by azobisisobutyronitrile, from 60 Ā°C to 70 Ā°C given that: Ep = 34 kJ molāˆ’1 Et = 1 kJ molāˆ’0 1 Ed = 126 kJ molāˆ’1 Assume that the concentration of monomer and initiator and the values of f and q remain unchanged when the temperature is increased.

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