Acetic acid, or vinegar , boils sooner than water. if you had a mixture of acetic acid and water, you could separate it by ?

Heating the mixture to a temperature above the boiling point of acetic acid, but below 100°C (the boiling point of water). The vapours from the acetic acid rise, and go into a tube. They are then condensed within the tube, and run off into a separate storage area. Because water can exist as a gas at pretty much any temperature above 0°C, it will result in an impure mixture, but repeatedly doing this will get the acetic acid to the desired purity.