The first-order rearrangement of ch3nc is measured to have a rate constant of 3.61 × 10–15 s–1 at 298 k and a rate constant of 8.66 × 10–7 s–1 at 425 k. determine the activation energy for this reaction.

The activation energy for this reaction, Ea = 159.98 kJ/mol

Explanation:

Using the Arrhenius equation as:

Where, Ea is the activation energy.

R is the gas constant having value 8.314 J/K.mol

K₂ and K₁ are the rate constants

T₂ and T₁ are the temperature values in kelvin.

Given:

K₂ = 8.66×10⁻⁷ s⁻¹ , T₂ = 425 K

K₁ = 3.61×10⁻¹⁵ s⁻¹ , T₁ = 298 K

Applying in the equation as:

Solving for Ea as:

Ea = 159982.23 J /mol

1 J/mol = 10⁻³ kJ/mol

Ea = 159.98 kJ/mol

  the grams     of oxygen gas   that can be produced     is 20.6   grams of o₂

calculation

2liclo₃ →   2 licl + 3 o₂

step 1:   find the moles of liclo₃

moles = mass÷ molar mass

from periodic table the molar mass of liclo₃ =6.9 +35.5   +(16 x3) =90.4 g/mol

moles=38.7 g÷90.4 g/mol=0.4281   moles

step 2:   use the   mole ratio   to calculate the moles of o2

from equation above, liclo₃: o₂   is 2: 3  

therefore the moles of   o₂=0.4281 moles x3/2 =0.6422   moles

step 3: find mass   of o₂

mass= moles x molar mass

from periodic table the   molar mass of   o₂ = 16 x2= 32 g/mol

mass=0.6422   moles   x   32 g/mol = 20.6 grams of o₂

im guessing the west of station b