Mark the false statements. a. a π bond restricts rotation about the bond axis. b. bonds formed from the overlap of atomic s orbitals are always σ bonds. c. a triple bond consists of one π bond and two σ bonds. d. end-to-end overlap of orbitals results in a bond with electron density above and below the bond axis. e. a π bond consists of two pairs of electrons. f. two σ bonds comprise a double bond.

Part f - example: finding two forces (part i) two dimensional dynamics often involves solving for two unknown quantities in two separate equations describing the total force. the block in (figure 1) has a mass m=10kg and is being pulled by a force f on a table with coefficient of static friction îľs=0.3. four forces act on it: the applied force f (directed î¸=30â above the horizontal). the force of gravity fg=mg (directly down, where g=9.8m/s2). the normal force n (directly up). the force of static friction fs (directly left, opposing any potential motion). if we want to find the size of the force necessary to just barely overcome static friction (in which case fs=îľsn), we use the condition that the sum of the forces in both directions must be 0. using some basic trigonometry, we can write this condition out for the forces in both the horizontal and vertical directions, respectively, as: fcosî¸â’îľsn=0 fsinî¸+nâ’mg=0 in order to find the magnitude of force f, we have to solve a system of two equations with both f and the normal force n unknown. use the methods we have learned to find an expression for f in terms of m, g, î¸, and îľs (no n).

In positive numbers less than 1, the zeros between the decimal point and a non-zero number are blank significant

Asheet of steel 1.5 mm thick has nitrogen atmospheres on both sides at 1200oc and is permitted to achieve a steady-state diffusion condition. the diffusion coefficient for nitrogen in steel at this temperature is 6 x 10- 11 m2 /s, and the diffusion flux is found to be 1.2 x 10-7 kg/m2 -s. also, it is known that the concentration of nitrogen in the steel at the high-pressure surface is 4 kg/m3 . how far into the sheet from this high-pressure side will the concentration be 2.0 kg/m3 ? assume a linear concentration profile.