Does mars has a bulge near its equator ?

In the derivation of rrkm theory, a factor of 1/2 is introduced when equalizing the rates of formation and decomposition of activated complex as keal-hr) = ko this is clearly against the assumption of transition state theory that states all the activated complex in the transition state iss going to the product. find the reason why this factor is introduced here.

Idon’t quite understand this problem

Aballoon is rising vertically upwards at a velocity of 10m/s. when it is at a height of 45m from the ground, a parachute bails out from it. after 3s he opens his parachute and decelerates ata a constant rate 5m/s.when. (a) what was the height of the parachutist above the ground when he opened his parachute? (b)how far is the parachutist from the balloon at t=3s? (c)with what velocity does the parachutist hit the ground? (d)after how long does the parachutist hit the ground after his exist from the balloon?