Please help me choose the correct answer

Apple pie is removed from 350 degree oven. temperature of the pie t minutes after being removed id given by the function t(t)=72+268e-0.068t

Which situation can be modeled by the inequality 5 + 10w ≥ 45? a. you start with $5 and save $10 a week until you have at least $45. b.you start with 5 baseball cards and purchase 10 cards every week until you have at most 45 cards. c.you start with 5 water bottles and purchases cases of 10 water bottles each until you have a total of 45 water bottles. d.you spend $5 plus $10 per week until you have less than $45.

He mass of a single atom of carbon can be found by dividing the atomic mass (12.01 g) by 6.022 x 10^23. which is the mass of a single carbon atom, correctly written in scientific notation with the correct number of significant figures?