Round 25446 to 1 significant figure

The ratio pv to nrt is plotted against pressure for ch4 at 0°c and 200°c. why does the curve for 0°c drop below the horizontal line for an ideal gas whereas the curve for 200°c does not?

Need solving this second acceleration problem.

Adrawer contains 12 identical white socks, 18 identical black socks and 14 identical brown socks. what is the least number of socks you must choose, without looking, to be certain that you have chosen two socks of the same colour?