Can I get help please

(a) calculate the molarity of a solution that contains 0.0345 mol nh4cl in 400 ml of solution. (b) how many moles of hno3 are present in 35.0 ml of a 2.20 m solution of nitric acid? (c) how many milliliters of 1.50 m koh solution are needed to supply 0.125 mil of koh ?

Find the gradient of f(x,y,z)equals=left parenthesis x squared plus y squared plus z squared right parenthesis superscript negative 1 divided by 2 baseline plus ln left parenthesis x right parenthesis x2+y2+z2−1/2+ln(xyz) at the point left parenthesis negative 2 comma 1 comma negative 2 right parenthesis(−2,1,−2).

Which expression converts 45 degree to radians