Which of the following belong to a category called the main group of elements

First of all, you didn't show what the choices were. Type in the choices again so we can help you. : D

check the picture below.

well, the angle at the vertex d is clearly not a right-angle, let's check for the one at the vertex f which does look like,   however if it's indeed, that means ef is perpendicular to df, in which case their slopes will be negative reciprocal of each other.

so the negative reciprocal of the slope of ef is 1, however the slope of df is not 1, is 1/2, so nope, they're not perpendicular lines.