Air is contained inside a vertical piston-cylinder assembly by a piston of mass 105 kg and face area of 0.05 m2 . The mass of air inside the cylinder is 20 grams, and the air initially occupies a volume of 50 liters. The atmosphere exerts a pressure of 101.3 kPa on the top of the piston. The volume of the air slowly decreases to 0.005 m3 , while maintaining constant pressure, as the specific internal energy of the air decreases by 175 kJ/kg. Neglecting friction between the piston and the cylinder wall, determine the heat between the surroundings and the air inside the piston-cylinder assembly in kJ