MeCN solutions of NbCl5 and HF contain a mixture of octahedral [NbF6] , [NbF5Cl], [NbF4Cl2] , [NbF3Cl3] and [NbF2Cl4] . Predict the number and coupling patterns of the signals in the 19F NMR spectrum of each separate component in this mixture, taking into account possible isomers. (Assume static structures and no coupling to 193Nb.)

Aplate clutch has a single pair of mating friction surfaces 250-mm od by 175-mm id. the mean value of the coefficient of friction is 0.30, and the actuating force is 4 kn. a) find the maximum pressure and the torque capacity using the uniform-wear model. b) find the maximum pressure and the torque capacity using the uniform-pressure model.

Apiston-cylinder device contains 0.1 m3 of liquid water and 0.9 m3 of water vapor in equilibrium at 800 kpa. heat is transferred at constant pressure until the temperature of water reaches 350 °c. determine (a) the quality of water at the initial state (b) the work associated with this process, (c) the heat associated with this process.

An open feedwater heater operates at steady state with liquid entering at inlet 1 with t? = 40°c and pl = 1 .2 mpa. water vapor att2-200°c and p2 = 1.2 mpa enters at inlet 2. saturated liquid water exits with a pressure of pa 1.2 mpa. neglect heat transfer with the surroundings and all kinetic and potential energy effects, determine the mass flow rate of steam at inlet 2 if the mass flow rate of liquid water at inlet 1 is given as 2 kg/s.