D = Γα²/6 applies to any diffusing species in any cubic lattice. Show that this is true for vacancy diffusion in a pure FCC metal. (hint: consider two adjacent {111} planes and determine what fraction of all possible jumps result in the transfer of a vacancy between the two planes. Is the same result obtained by considering adjacent {100} planes?

Atank with constant volume contains 2.27 kg of a mixture of water phases (liquid-vapor). in the initial state the temperature and the quality are 127 °c and 0.6, respectively. the mixture is heated until the temperature of 160 oc is reached. illustrate the process in a t-v diagram. then, determine (1) the mass of the vapor in kg at the initial state, (2) the final pressure in kpa.