What mass of hcl gas must be added to 1.00 l of a buffer solution that contains [aceticacid]=2.0m and [acetate]=1.0m in order to produce a solution with ph = 4.11?

PH of acidic buffer = pKa + log [CH₃COONa - HCl] / [CH₃COOH + HCl]
pKa of CH₃COOH = 4.74
Concentration of acetic acid in buffer = 2.0 M
Concentration of sodium acetate = 1.0 M
Concentration of HCl must add = x
pH = 4.74 + log (1-x) / (2+x) = 4.11
x = concentration of HCl must be added = 0.43 M
number of moles of HCl = M * V = 0.43 * 1 = 0.43 mol
mass of HCl must be added = 0.43 * 36.5 = 15.7 g
 

For cyclohexane compounds drawn in a chair conformation:   -axial bonds are vertical  -equatorial bonds are parallel to two bonds within the ring.  thus, as i assume the chair conformation is drawn:   -the x group is in an axial position, as are the five other vertical bonds.  -three axial bonds are on the top face of the ring  -the other three axial bonds are on the bottom face  the position of the second substituent on each ring carbon is equatorial.  gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other.  drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1.  click this link and watch some academic videos that may you more understand the topic