What concentration of the lead ion, pb2+, must be exceeded to precipitate pbf2 from a solution that is 1.00×10−2 m in the fluoride ion, f−? ksp for lead(ii) fluoride is 3.3×10−8 ?

Answer is: concentration of Pb²⁺ must be exceeded is 3.3·10⁻⁴ M.

Chemical reaction : Pb²⁺(aq) + 2F⁻(aq) → PbF₂(s).

Ksp(PbF₂) = 3.3·10⁻⁸.
c(F⁻) = 0.01 M.
Ksp(PbF₂) = c(Pb²⁺) · c(F⁻)².
c(Pb²⁺) = Ksp(PbF₂) ÷ c(Cl⁻)².
c(Pb²⁺) = 3.3·10⁻⁸ ÷ (0.01 M)².
c(Pb²⁺) = 0.000000033 M³ ÷ 0.0001 M².
c(Pb²⁺) = 0.00033 M = 3.3·10⁻⁴ M.

explanation:

venn diagram is pictorial representation with of circles showing the relation between two finite sets or things. the intersection part of two circles conveys the relation present in between those sets or things.

here in the venn diagram of sand and salt two circles represent sand and salt. but the area falling under the intersection of these circle represents the mixture of sand and salt.

so, in a venn diagram the mixture will be placed in a middle that is in between the intersection of two circles.

a mercury barometer is a device that uses the physical properties of mercury in a tube to measure barometric pressure. mercury barometers are used for : -

1. measurement of atmospheric pressure  

2. determining the altitude of a place

3. weather forecasting

4. calibration and checking of aneroid barometers

5. application in fluid mechanics

6. measurement of pressure in aircrafts

7. surface weather analysis

8. preparation of barographs

9. usage in physical sciences like physics, astronomy & chemistry

10. preparation of aircraft altimeters

characteristics of mercury barometer : -

1.used to define and measure atmospheric pressure.

2.on the average at sea level the column of mercury rises to a height of about 760 mm.

3.this quantity is equal to 1 atmosphere.

4.it is also known as standard atmospheric pressure.

5.a barometer in which the weight of a column of mercury in a glass tube with a sealed top is balanced against that of the atmosphere pressing on an exposed cistern of mercury at the base of the mercury column, the height of the column varying with atmospheric pressure.