A100.0 ml sample of 0.18 m hclo4 is titrated with 0.27 m lioh. determine the ph of the solution after the addition of 100.0 ml of lioh.

(I think you have a mistake in your question as the addition is 30mL, not 100mL)
when PH = - ㏒[H+]
and here we have HClO4 is the strong acid
So PH = - ㏒[HClO4]

moles of HClO4 = 0.1 L *0.18 m = 0.018 M
moles of LiOH = 0.03 L * 0.27 m = 0.0081 M
when the total volume = 0.1L + 0.03L =  0.13 L
∴ [HClO4] = (0.018-0.0081)/0.13 L
                 = 0.076 M
PH = -㏒ 0.076
      = 1.12

For cyclohexane compounds drawn in a chair conformation:   -axial bonds are vertical  -equatorial bonds are parallel to two bonds within the ring.  thus, as i assume the chair conformation is drawn:   -the x group is in an axial position, as are the five other vertical bonds.  -three axial bonds are on the top face of the ring  -the other three axial bonds are on the bottom face  the position of the second substituent on each ring carbon is equatorial.  gauche groups must be on an adjacent carbon such as carbon 6 and carbon 2, and also gauche groups are rotated by 60 degrees relative to each other.  drawing the newman projections for c1–c2 and c1–c6 aids in visualizing the groups that are gauche to the y group on c1.  click this link and watch some academic videos that may you more understand the topic