If enought heat was removed from water. what will it change into and why

Water (2510 g ) is heated until it just begins to boil. if the water absorbs 5.09×105 j of heat in the process, what was the initial temperature of the water?

If a solution is considered basic, then a) the hydroxide ion and hydronium ion concentrations are equal. b) the hydroxide ion concentration is less than the hydronium ion concentration. c) the hydronium ion concentration is greater than the hydroxide ion concentration. d) the hydroxide ion concentration is greater than the hydronium ion concentration.

Assuming complete dissociation of the solute, how many grams of kno3 must be added to 275 ml of water to produce a solution that freezes at -14.5 c? the freezing point for pure water is 0.0 c and k_f is equal to 1.86 c/m