Define acid and base according to lewis theory, arrhenius theory and lawn theory

Three principal theories about acid-base are,

1. Arrhenius theory

2. Bronsted-Lowry theory

3. Lux-Flood definition

4. Lewis theory

5. Usanovich definition

1. According to the Arrhenius, acids give up hydrogen ion in aqueous medium and a base give up hydroxyl ion in its aqueous medium. Examples are aqueous solution of HCl, CH3COOH, PhCOOH, and H2SO4. These give up H+ in an aqueous medium. Aqueous solutions of NaOH, Ca (OH)2 are Arrhenius bases.

Arrhenius theory has some limitations. This theory cannot explain the acidic nature of BF3 or basic behavior of NH3. This theory fails to give any explanation about acidity and basicity which does not produce H+ and OH- in their aqueous solutions.

2. According to the Bronsted-Lowry, an acid releases proton and a base accepts proton. NH3 accepts proton and forms ammonium ion, so ammonia acts as a base.

But this theory also has limitations. According to this theory acidic behavior of BF3 still cannot be explained.

3. Lux-Flood describes the acid-base theories based on oxide ion transformation. It gives clear explanation for acid-bases theories of non-protonic system. According to them, a base will donate the oxygen atom and an acid will accept oxygen atom.

4. According to the Lewis theory, acids are those substances which accept electron pair and base are those substances which donates electron pairs. Lewis theory can explain the acidic nature of BF3. In BF3, B is two electrons short to fulfil its octet. So it can accept a pair of electrons from an electron donating substituent. So it is an electron pair acceptor compound and acts as an acid.

Substances which have π electrons can donate electron pair to an electron deficient substance and acts as a base. Ethylene and acetylene is Lewis bases. AlCl3, PCl3 are Lewis acids.

5. According Usanovich, an acid is some chemical species which would react with bases and yields cations or accepts anions or electrons. A base is some chemical species which would react with acids, yield anions or electrons or combine with cations.

Explanation:

answer: the enthalpy of the overall chemical reaction is +87.88 kj or +88 kj.

according to hess's law, the overall enthalpy of a reaction is the difference between the sum of enthalpy values of all the products and the sum of enthalpy values of all the reactants.

δh(reaction) = ∑nδh(products) - ∑nδh(reactants)

δh(reaction) = [δh +δh] - [δh]

δh(reaction) = [1(-287.02) + 1(0) ] - [1(-374.9)] kj = +87.88 kj

here, δh (pcl3) = -287.02 kj, δh(cl2) = 0, δh(pcl5) = -374.9 kj

therefore, enthalpy of the overall reaction is +87.88 kj or +88 kj.

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