Please help solve the attached. it's urgently needed. My exams starts on Monday

Mike and mitchell decide to have a foot race. they mark off a stretch of 100 yards, and recruit cindy to work the stopwatch. after running the race and looking at the results, cindy declared that mitchell was the fastest. so how did the boys times compare?

100 grams of molten lead (600°c) is used to make musket balls. if the lead shot is allowed to cool to room temperature (21°c), what is the change in entropy (in j/k) of the lead? (for the specific heat of molten and solid lead use 1.29 j/g⋅°c; the latent heat of fusion and the melting point of lead are 2.45 × 104 j/kg and 327°c, respectively.)

The vapor pressure of ethanol is 1.00 × 102 mmhg at 34.90°c. what is its vapor pressure at 61.61°c? (δhvap for ethanol is 39.3 kj/mol.)