Calculate the potential (emf) of a working galvanic cell that is based on these two half cells and standard potentials (both written as reduction reactions) in an aqueous solution. Cr3+(aq) → Cr2+(aq) E°(Cr3+/Cr2+) = â’0.50 V IO2â’(aq) → I2(aq) E°( IO2â’/I2) = +1.80 V The pH of this cell is 14, and the concentrations of species are: Cr3+ is 0.5 M, Cr2+ is 0.2 M, IO2â’ is 0.5 M and I2 is 0.8 M.

Consider the reduction reactions and their equilibrium constants. cu+(aq)+e−↽−−⇀cu(s)pb2+(aq)+2e−↽−−⇀pb(s)fe3+(aq)+3e−↽−−⇀fe(=6.2×108=4.0×10−5=9.3×10−3 cu + ( aq ) + e − ↽ − − ⇀ cu ( s ) k =6.2× 10 8 pb 2 + ( aq ) +2 e − ↽ − − ⇀ pb ( s ) k =4.0× 10 − 5 fe 3 + ( aq ) +3 e − ↽ − − ⇀ fe ( s ) k =9.3× 10 − 3 arrange these ions from strongest to weakest oxidizing agent.

)benzene and toluene form nearly ideal solutions. consider an equimolar solution of benzene and toluene. at 20 °c the vapour pressures of pure benzene and toluene are 9.9 kpa and 2.9 kpa, respectively. the solution is boiled by reducing the external pressure below the vapour pressure. calculate (i) the pressure when boiling begins, (ii) the composition of each component in the vapour, and (iii) the vapour pressure when only a few drops of liquid remain. assume that the rate of vaporization is low enough for the temperature to remain constant at 20 °c.

In a heat of an engine, if 700 j enters the system, and the piston does 400 j of work what is the final internal (thermal) energy of the system if the initial energy is 1,500 j