5. Select the answer for both questions

Both 1,2−dihydronaphthalene and 1,4−dihydronaphthalene may be selectively hydrogenated to 1,2,3,4−tetrahydronaphthalene. one of these isomers has a heat of hydrogenation of 101 kj/mol (24.1 kcal/mol), and the heat of hydrogenation of the other is 113 kj/mol (27.1 kcal/mol). match the heat of hydrogenation with the appropriate dihydronaphthalene.

A3.37-mg sample of protein was chemically digested to convert its nitrogen into ammonia and then diluted to 100.0 ml. then 10.0 ml of this solution was placed in a 50-ml volumetric flask and treated with 5 ml of phenol solution plus 2 ml of sodium hypochlorite solution. the sample was diluted to 50.0 ml, and the absorbance at 625 nm was measured in a 1.00-cm cuvette and found to be 0.486. for reference, a standard solution was prepared from 10.0 mg of nh4cl (molar mass = 53.49 grams/mole) dissolved in 1.00 l of water. then 10.0 ml of this standard was placed in a 50-ml volumetric flask, treated in the same manner as the unknown, and the absorbance found to be 0.323. finally, a reagent blank was prepared using distilled water in place of unknown, it was treated in the same manner as the unknown, and the absorbance found to be 0.076. calculate the weight percent of nitrogen in the protein.

Modern pennies are composed of zinc coated with copper. a student determines the mass of a penny to be 2.482 g and then makes several scratches in the copper coaling (to expose the underlying zinc). the student puts the scratched penny in hydrochloric acid, where the following reaction occurs between the zinc and the hcl (the copper remains undissolved): zn(s) + 2 hcl(aq) → h2(g) + zncl(aq)the student collects the hydrogen produced over water at 25 °c. the collected gas occupies a volume of 0.899 l at a total pressure of 79 j mmhg. calculate the percent zinc (by mass) in the penny. (assume that all the zn in the penny dissolves.)