Chemistry, 29.11.2021 08:20 biba54

Substitution reaction

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Substitution reaction
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Answer from: Quest

answer : third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

explanation :

let us write down the given equations

equation 1 : $4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

equation 2 : $2x (s) + 3cl_{2} (g) \rightarrow 2xcl_{3} (s) h rxn = -800 kj/mol$

equation 3 : $4xcl_{3} (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) + 6cl_(2} h rxn = -200 kj/mol$

let us use hess's law to find out which 2 equations can be added to get the third equation.

let us reverse equation 2 and multiply it by 2. the new equation that we get is,

equation 4 : $4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+800) \times 2 kj/mol$

let us add equation 1 & 4

$4x (s) + 3o_{2} (g) \rightarrow 2x_{2}o_{3} (s) h rxn = -600 kj/mol$

$4xcl_{3} (s) \rightarrow 4x (s) + 6cl_{2} ( h rxn = (+1600) kj/mol$

$4xcl_{3} )s) + 3o_{2} \rightarrow 2x_{2}o_{3} (s) + 6cl_{2} (g) h rxn = (+1000) kj/mol$

the above equation is similar to equation 3 but has different value for dhrxn.

therefore third trial had the contaminated sample and the correct value for dhrxn should be 1000 kj/mol

Answer from: Quest

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Answer from: Quest

I'm sorry but i'm only grade

Answer from: Quest

Note that 2 mol dm⁻³ = 2 mol/(dm³)outline: we're given the concentration of hcl, which is 2 mol dm⁻³ (cubic meters in the denominator can represent volume, so i know this is concentration). we're an amount of calcium carbonate caco₃, which is 5 g. we're presented with a chemical equation which includes caco₃ and hcl. we are told to find the volume of hcl. from what we see so far, this seems to be a stoichiometry problem. we'll have to use the given information about calcium carbonate to find the amount of moles of hcl needed to fully react with calcium carbonate. then we'll have information about the moles of hcl and the concentration of hcl; that will be enough to figure out volume according to the formula concentration = moles / volume.======all the answer choices are not in dm.convert the given concentration so that it uses cm⁻³.we can use conversion factors. we have to cube our conversion factors so that dimensional analysis works.we can convert to meters first, using the fact that 10 dm = 1 m ⇔ 10³ dm³ = 1 m³then we use the fact that 10² cm = 1 m ⇔ (10² cm)³ = (1 m)³ ⇔ 10⁶ cm³ = 1 m³so converting: $\dfrac{\text{2 mol}}{\text{dm}^{3}} \cdot \dfrac{\text{10}^3\text{ dm}^3}{\text{1 m}^3} \cdot \dfrac{\text{1 m}^3}{10^6\text{ cm}^3} \\ \\ = \dfrac{\text{2 mol}}{1} \cdot \dfrac{\text{10}^3}{1} \cdot \dfrac{1}{10^6\text{ cm}^3} \qquad \text{\footnotesize cancelling units} \\ \\ = \dfrac{2\text{ mol}}{10^3 \text{ cm}^3} \\ \\ = 0.002\text{ mol/cm}^3$ now we have to find the moles of hydrochloric acid neededfind the moles of calcium carbonate. we have to find the molar mass of calcium carbonate, caco₃, which can be found by molar mass = (mass ca) + (mass c) + 3(mass o) = 40 + 12 + 3(16) = 100 g/molconvert the given 5 g to moles: mol caco₃ = 5 g caco₃ * 1 mol/(100 g) = 0.05 mol caco₃use stoichiometry (ratios) to figure out the moles of hcl needed. ratio wise, there's 2 hcls for every caco₃, so use dimensional analysis mol hcl = mol caco₃ * (2 mol hcl) / (1 mol caco₃) = 0.05 mol hcl * 2 = 0.1 mol hcl we have 0.1 mol hcl and concentration of hcl (0.002 mol/cm³).we need to find volumesince concentration = moles / volume, rearrange to get volume = moles / concentration volume = 0.1 mol / (0.002 mol/cm³) volume = 50 cm³

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Substitution reaction

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