if i over titrate when standardizing will the calculated concentration be higher, lower or the same as the true value?

Match the mixture with the substance// i really need on this guys (it’s a pic btw)

4.25g sample of solid ammonium nitrate dissolves in 60.0g of water in a coffee-cup calorimeter, the temperature drops from 22.0 c to 16.9 c. assume that the specific heat of the solution is the same as that of pure water. calculate delta(h) (in kj/mol nh4no3) for the solution proces.

What is the number of neutrons in an atom with atomic mass of 35