I am stuck on these two problems. Help would be very much appreciated!

Scientific evidence tells us that the cause of earths four season is the tilt of earth as it revolves around the sun. the student is instructed to illustrate this information in a science notebook. how will the student illiterate winter in the northern hemisphere?

Sulfur dioxide and oxygen react to form sulfur trioxide during one of the key steps in sulfuric acid synthesis. an industrial chemist studying this reaction fills a 25.0l tank with 4.5 mol of sulfur dioxide gas and 4.5 mol of oxygen gas at 30.°c. he then raises the temperature, and when the mixture has come to equilibrium measures the amount of sulfur trioxide gas to be 1.4 mol. calculate the concentration equilibrium constant for the reaction of sulfur dioxide and oxygen at the final temperature of the mixture. round your answer to 2 significant digits.

Estimate the molar mass of the gas that effuses at 1.6 times the effusion rate of carbon dioxide.