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Idon’t understand this page, can someone ?

Asyringe contains 56.05 ml of gas at 315.1 k. what volume will that gas occupy if the temperature is increased to 380.5 k? a) 12.41 b) 46.42 c) 67.68 d) 81.74

You are making a solution of calcium chloride dissolved in water. you add solid, stir, and it dissolves. you add just a spatula tip full, stir, and the solid does not dissolve. how could you describe the solutions before and after adding the spatula tip amount