Terephthalic acid is composed of carbon, hydrogen, and oxygen. When 0.6943 g of terephthalic acid was subjected to combustion analysis, it produced 1.471 g CO2 and 0.225 g H2O. What is its empirical formula?

when 25.0 ml of 0.700 mol/l naoh was mixed in a calorimeter with 25.0 ml of 0.700 mol/l hcl, both initially at 20.0 °c, the temperature increased to 22.1 °c. the heat capacity of the calorimeter is 279 j/°c.

the equation for the reaction is:

naoh + hcl → nacl + h₂o

moles of hcl = 0.0250 l hcl ×

0.700

mol hcl

1 l hcl = 0.0175 mol hcl

volume of solution = (25.0 + 25.0) ml = 50.0 ml

mass of solution = 50.0 ml soln ×

1.00

ml soln

= 50.0 g soln

δt=t2-t1

= (22.1 – 20.0) °c = 2.1 °c

the heats involved are

heat from neutralization + heat to warm solution + heat to warm calorimeter = 0

q1+q2+q3=0

nδh+mcδt+cδt=0

0.0175 mol ×

δh

+ 50.0 g × 4.184 j·g⁻¹°c⁻¹ × 2.1 °c + 279 j°c⁻¹ × 2.1 °c = 0

0.0175 mol ×

δh

+ 439.32 j + 585.9 j = 0

0.0175 mol ×

δh

= -1025.22 j

δh=1025.22j0.0175 mol= -58 600 j/mol = -58.6 kj/mol

answer: the value of enthalpy change will be -152.80 kj.

solution:

pressure = 1atm , temperature = = 298 k

given that pressure and temperature are same in both gases , the number of moles of both gases can be determined by the ideal gas equation.

according to reaction 3 moles no are reacting with 1 mol of ,then 0.49 mol of no will react with moles of ozone that is 0.16 moles of ozone. since, no is limiting reagent and is an excessive reagent.

enthalpy change for the reaction between the given volumes of the gases is :