PLEASE HELP WITH question 2 and 3 please

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Observation and experimentation have led many scientists to accept a theory about the origin of the universe. this theory is called the big bang theory. scientific evidence collected and observed by scientists around the world suggests that the universe is ever expanding from a hot and dense initial state. what makes this a scientific theory? (2 points)

Using this reversible reaction, answer the questions below: n2o4 2no2 (colorless) (reddish-brown) -as the temperature increased, what happened to the n2o4 concentration? -was the formation of reactants or products favored by the addition of heat? -which reaction is exothermic? right to left or left to right? -if the change of enthalpy of this reaction when proceeding left to right is 14 kcal, which chemical equation is correct? n2o4 2no2 + 14 kcal n2o4 2no2, hr = +14 kcal n2o4 + 14 kcal 2no2 n2o4 2no2, hr = -14 kcal