HELP PLEASE WILL MARK BRAINLIEST

When will le chatelier's principle come into effect? at the beginning of a reaction, when there are only reactants when a reaction has reached chemical equilibrium when a catalyst is added to a reaction mixture when a reaction is occurring but not yet at equilibrium

Can someone me with questions 15 to 17 plz.

13. a covalent bond between two atoms is likely to be polar if: a. one of the atoms is much more electronegative than the other. b. the two atoms are equally electronegative. c. the two atoms are of the same element. d. the bond is part of a tetrahedrally shaped molecule. e. one atom is an anion.