At 298 K, H = -1652 kJ/mol and S = 0.097 kJ/(K•mol). What is the Gibbs free energy of the reaction? A.-1681 kJ

B. 67,000 kJ

C. 225 kJ

D. -745 kJ

it can be observed without changing the identity of the object.

it depends on what substance you're talking about as well as many other factors. in quantum mechanics, the observation of particles affects the observers ability to measure certain properties. for example: you can know the velocity of a particle, but you can't know it's position; or you can know it's position, but not it's velocity. it's like trying to find out where a grain of sand is by throwing other grains of sand at it. once you find out where it is, it's been moved. it's also like trying to find an answer to the question of whether or not a tree falling in a forest makes a sound if nobody is there to hear it. paradoxically, the only way to find out is to be there and hear it.

answer : the correct answer is 2) hno₃ and naoh .

arrhenius concept of acid and base :

acid :

according to arrhenius acid are those which release h⁺ or hydronium ion (h₃o⁺) in aqueous solution .

example : hcl +h₂o ↔ h₃o⁺ + cl⁻

hcl is giving h₃o⁺ ion in water , hence it is an arrhenius acid .

base :

according to arrhenius , bases are those which releases oh⁻ ions in aqueous solution .

example : koh (aq) ↔ k⁺ + oh⁻

since koh is producing oh⁻ ions hence , it is an arrhenius base .

checking the options :

1) ch₃oh and naoh :

ch₃oh is known as methanol , an organic compound , which is neutral compound . the dissociation of ch₃oh is negligible . it is very very weak acid (ka = 3.2 * 10 ⁻¹² ) .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻ . hence it is an arrhenius base

it can be concluded that ch₃oh and naoh is not arrhenius acid and base.

2) hno₃ and naoh :

hno₃ is an ionic compound which gives ions h⁺ and no₃⁻ ion in aqueous solution as:

hno₃ + h₂o ↔ h₃o⁺ + no₃⁻

since it is giving h⁺ ion . hno₃ is arrhenius acid .

naoh being ionic gives na⁺ and oh⁻ ions in aqueous solution as :

naoh ↔ na⁺ + oh⁻

. hence it is an arrhenius base .

it can be said that hno₃ and naoh are arrhenius acid and base.

3) ch₃oh and hcl

as discussed ch₃oh is neutral compound .

while hcl in aqueous solution dissociates to give h⁺ and cl⁻ ions as :

hcl + h₂o→ h₃o⁺ + cl⁻ . so hcl is arrhenius acid .

hence , ch₃oh and hcl are not arrhenius acid and base.

4) hno₃ and hcl :

hno₃ as discussed gives h⁺ in aqueous solution , while hcl also gives h⁺ in aqueous solution .

hence both hno₃ and hcl are arrhenius acid they are not acid and base .

so the arrhenius acid and base are 2) hno₃ and naoh.