Calculate the following for test tube 1 and for test tube 2, and record the results in the table: 1-the number of moles of copper(II) sulfate used (Use 159.60 grams/mole as the molar mass of copper(II) sulfate.)
2-the heat absorbed by the water, in joules (Use Q = mCΔT, where 10.0 milliliters of water has a mass of 10.0 grams. Use 4.186 joules/gram degree Celsius as water’s specific heat capacity.)
3-the change in internal energy of the copper(II) sulfate (Assume that the energy released by the copper(II) sulfate is absorbed by the water.)
4-the reaction enthalpy, in joules/mole

Test tube 1 Test tube 2
Moles of copper(II) sulfate
Heat absorbed by water (J)
Change in internal energy (J)
Reaction enthalpy (J/mol)

The answer to your question really depends on three things: how much water you have, how cold it is to start out, and how cold the things around it are. water actually freezes when it gets to 32 degrees fahrenheit (0 degrees celsius), but the time it takes to get there may be different.  let's start with the first. if you take two glasses, and fill one with a tiny bit of water, and the other about halfway, then put them both in the freezer, the one with less water will freeze first (you can try this at home, but i recommend using plastic cups and not glass ones).  now let's move on to the second part. let's say you have two glasses, and you fill one with really cold water that has been in the refrigerator, and the other with really hot water from the sink. if you put both of them in the freezer, the one that started out colder will freeze first.  for the third part, let's imagine that you have two glasses with the same amount of water in them, and the water is at the same temperature. imagine putting one outside on a really really cold day in georgia, and having a friend in alaska put one outside on the same day. since it would be so much colder in alaska, the glass of water there would freeze before yours.  so, if you took a tiny bit of really cold water in a glass, and put it outside on a cold day in alaska, it would freeze a lot faster than a big glass of hot water outside on a cold day in georgia. 

The internal energy of the system we can term it as total potential energy and kinetic energy. energy flows out of the surrounding from the system then we can say that the internal energy of the final state is lower than its initials. the sign of  δesystem is negative.δesystem = efinal - einitial=-ve  efinal  ∠einitial.

Ibelieve it would be hcl