A buffer solution contains 0.475 M nitrous acid and 0.302 M sodium nitrite . If 0.0224 moles of potassium hydroxide are added to 150 mL of this buffer, what is the pH of the resulting solution

The pH of the resulting solution will be 3.001

Explanation:

Molarity is calculated by using the equation:

         ......(1)

We are given:

Moles of NaOH = 0.0224 moles

Molarity of nitrous acid = 0.475 M

Molarity of sodium nitrite = 0.302 M

Volume of solution = 150 mL = 0.150 L          (Conversion factor: 1 L = 1000 mL)

Putting values in equation 1, we get:

The chemical equation for the reaction of nitrous acid and NaOH follows:

I:                0.07125     0.0224     0.0453

C:             -0.0224     -0.0224   +0.0224

E:              0.04885         -          0.0677

The power of the acid dissociation constant is the negative logarithm of the acid dissociation constant. The equation used is:

       ......(2)

We know:

for nitrous acid =

Using equation 2:

To calculate the pH of the acidic buffer, the equation for Henderson-Hasselbalch is used:

        .......(3)

Given values:

Putting values in equation 3. we get:

Hence, the pH of the resulting solution will be 3.001

when—without warning—something provokes your anger, you may struggle not to succumb to it. since what typically makes you mad is feeling powerless in the face of what seems unfair, your anger is mostly an attempt at a “quick fix” to right the balance. it’s as though you’re raising a fist in protest, proclaiming that you’re not going to capitulate to such injustice.

there are, however, a multitude of problems related to this immediate, push-back reaction of anger. and probably the key one is that almost never does it resolve the issue that gave rise to it. such reactive anger is probably best understood as self-defeating. as david burns, the author of the seminal self- book feeling good, observes: if realistically, acting on your anger is to make any sense, it needs to meet two criteria—which, in almost every case, is frankly impossible. that is, your anger must:

be directed toward a person who has intentionally (and needlessly) behaved in a hurtful way toward you; and

be beneficial or advantageous to you (i.e., assist you in achieving a desired goal).

i think you’ll agree that only rarely can you claim that your anger is both warranted and , whether to yourself or the relationship.

so let me offer you a two-step alternative to abandoning your better judgment and giving in to the temptation of anger—one that should neutralize your anger in seconds. or, when you’re really angry, in minutes.

but keep in mind that you must really want to execute these steps, be sufficiently motivated to perform them. which means overcoming more unconscious resistance than you might ever have imagined. because there are many immediate “advantages” of anger that can interfere with your resolve, i’ll suggest a few of them that might interfere with your employing this powerful method to rid yourself of counter-productive anger.

explanation: