Three acid samples are prepared for titration by 0.01 M NaOH: 1. Sample 1 is prepared by dissolving 0.01 mol of HCl in 50 mL of water.
2. Sample 2 is prepared by dissolving 0.01 mol of HCl in 60 mL of water.
3. Sample 3 is prepared by dissolving 0.01 mol of HCl in 70 mL of water.

a. Without performing a formal calculation, compare the concentrations of the three acid samples (rank them from highest to lowest).
b. When the titration is performed, which sample, if any, will require the largest volume of the 0.01 M NaOH for neutralization?