Thermodynamics: Solve #1 & #3

How many moles of lead are in 1.50 x 10^12 atoms of lead? could you explain the answer as well and not just give it to me i am refreshing for finals and i need to know how to do it

In vapor-liquid equilibrium in a binary mixture, both components are generally present in both phases. how many degrees of freedom are there for such a system? the reaction between nitrogen and hydrogen to form ammonia occurs in the gas phase. how many degrees of freedom are there for this system? steam and coal react at high temperatures to form hydrogen, carbon monoxide, carbon dioxide, and methane. the following reactions have been suggested as being involved in the chemical transformation:

Ok, so i have 2 questions. try to answer them both: (the topic is fire) 1) how can you represent the chemical reaction of fire? 2) what kind of bond is formed in this chemical reaction