I messed up big time with my BABY<3 what should i do

Which of the following statements is true about planck’s law

Some liquids can be distilled, but only at temperatures that are so high that it is impractical, or so high the compound decomposes. explain why distillation such compounds at significantly less than atmospheric pressure (some degree of vacuum) would solve this problem.

4.25g sample of solid ammonium nitrate dissolves in 60.0g of water in a coffee-cup calorimeter, the temperature drops from 22.0 c to 16.9 c. assume that the specific heat of the solution is the same as that of pure water. calculate delta(h) (in kj/mol nh4no3) for the solution proces.